The crystal structure of [Ti(H2O)(6)](p-CH3C6H4SO3)(3).-3H(2)O consist
s of discrete cations, anions and solvate water molecules, all linked
by a hydrogen-bonding network. Each Ti ion lies on an inversion centre
and shows essentially octahedral coordination with Ti-O bonds in the
range 2.018 (5)-2.046 (6) Angstrom.