-C(6)H(3)ME(3))RU(D-PEN)](2)CL-2-CENTER-DOT-4H(2)O

Authors
CAPPER G DAVIES DL FAWCETT J RUSSELL DR
Citation
G. Capper et al., -C(6)H(3)ME(3))RU(D-PEN)](2)CL-2-CENTER-DOT-4H(2)O, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 578-580
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
4
Pages
578 - 580
Database
ISI
SICI code
0108-2701(1995)51:<578:->2.0.ZU;2-K
Abstract
The structure of the title compound, bis[mu-D-3-mercaptovalinato(1- )- 1 kappa N, 1:2 kappa(2)S;2 kappa N, 1:2 kappa S-bis[(eta(6)-mesitylene )ruthenium] dichloride tetrahydrate, Ru-2(C-5-H10NO2S)(2)(eta(6)-C9H12 )(2)]Cl-2.4H(2)O, contains tridentate anionic amino acid ligands, wher e the S atoms adopt bridging positions between the two Ru atoms result ing in a near planar Ru-S-Ru-S ring. The coordination at each Ru atom is completed by an amino N atom of the chelating ligand and the eta(6) -bonded mesitylene ring.