TRANS-[NI(ME(3)PH)(NHPH)(PME(3))(2)], A MONOMERIC NI-II-AMIDE COMPLEX

Authors
VANDERLENDE DD BONCELLA JM ABBOUD KA
Citation
Dd. Vanderlende et al., TRANS-[NI(ME(3)PH)(NHPH)(PME(3))(2)], A MONOMERIC NI-II-AMIDE COMPLEX, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 591-593
Citations number
14
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
4
Pages
591 - 593
Database
ISI
SICI code
0108-2701(1995)51:<591:TAMNC>2.0.ZU;2-#
Abstract
trans-Phenylamido(2,4,6-trimethylphenyl) phosphine)nickel(II), [Ni(C6H 6N)(C9H11) (C3H9P)(2)], has been synthesized and its crystal structure determined as part of an ongoing study of the reactivity and stabilit y of late transition metal-amide complexes, The geometry about the ami de N atom is planar, with a relatively long interaction with the metal center. The Ni atom exhibits square-planar coordination geometry with the PMe(3) ligands trans with respect to each other.