THE DIMER [PTCL2(P(C2H5)(3))((C6H5)-SOCH2)](2)

Authors
FRANCISCO RHP GAMBARDELLA MTP RODRIGUES AMGD DESOUZA GF FILGUEIRAS CAL
Citation
Rhp. Francisco et al., THE DIMER [PTCL2(P(C2H5)(3))((C6H5)-SOCH2)](2), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 604-606
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
4
Pages
604 - 606
Database
ISI
SICI code
0108-2701(1995)51:<604:TD[>2.0.ZU;2-7
Abstract
The structure determination of ']bis[cis-dichloro(triethylphosphine)pl atinum(II)] revealed the occurrence of discrete dimers, formed by two platinum complexes related by an inversion centre and connected by the (-CH2-CH2-) group attached to the S atoms, with the centre of the C-C bond [C13-C13' = 1.54(1) Angstrom] located at the origin. The metal h as a cis-square-planar coordination environment, and the geometries ab out the P and S atoms are tetrahedral.