DIBROMODIETHYLBIS(3H-IMIDAZOLE-2-THIONE-S)TIN(IV)

Authors
CASAS JS GONZALEZ AS SORDO J BARROS FJG VALLE G
Citation
Js. Casas et al., DIBROMODIETHYLBIS(3H-IMIDAZOLE-2-THIONE-S)TIN(IV), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 633-635
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
4
Pages
633 - 635
Database
ISI
SICI code
0108-2701(1995)51:<633:D>2.0.ZU;2-V
Abstract
The crystal structure of the title compound, [SnBr2(C2H5)(2)(C3H4N2S)( 2)], comprises discrete all-trans octahedral [SnBr(2)Et(2)(Himt)(2)] u nits (Himt = imidazol-2-thione) with the Sn atom coordinated to two et hyl C atoms [Sn-C = 2.158 (7) Angstrom], two Br atoms [Sn-Br = 2.759 ( 3) Angstrom], and two Himt S atoms [Sn-S = 2.771 (2) Angstrom]. The st ructural parameters suggest the presence of an intermolecular N-H ... Br hydrogen bond.