A BRANCHED POLYSILANE

Authors
LAMBERT JB PFLUG JL ALLGEIER AM CAMPBELL DJ HIGGINS TB SINGEWALD ET STERN CL
Citation
Jb. Lambert et al., A BRANCHED POLYSILANE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 713-715
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
4
Pages
713 - 715
Database
ISI
SICI code
0108-2701(1995)51:<713:ABP>2.0.ZU;2-R
Abstract
ylsilyl)-1,1,1,3,3,4,4,6,6,6-decamethylhexasilane, C22H66Si10, is a po lysilane in which the longest chain is made up of six Si atoms and bra nching occurs at the second and fifth Si atoms. Each of the two centra l Si atoms is bonded to a tris(trimethylsilyl)silyl group in an anti a rrangement. Bond lengths and angles are sufficiently close to normal t o indicate that the molecule is relatively unstrained.