Ks. Coley et al., SIMULTANEOUS REDUCTION AND CARBURIZATION OF ILMENITE, Metallurgical and materials transactions. B, Process metallurgy and materials processing science, 26(3), 1995, pp. 485-494
Citations number
22
Categorie Soggetti
Material Science","Metallurgy & Metallurigical Engineering
Western Australian ilmenite was reduced using ''Collie'' coal at tempe
ratures in the range 1587 to 1790 K to form carbon-saturated iron and
titanium oxycarbide. The oxycarbide phase formed from Ti3O5 at tempera
tures below 1686 K and from Ti2O3 at temperatures above 1686 K. At 168
6 K, both mechanisms occurred. The reaction rate was controlled by oxi
dation of carbon by carbon dioxide generated by reduction of the oxide
phase. The final product at temperatures up to 1686 K was a fine disp
ersion of titanium oxycarbide in iron. At 1790 K, the reducing oxide t
ended to remain intact and formed a coarser distribution. In general,
manganese impurities from the ilmenite were confined to the iron phase
in the product, although some of the coarser oxycarbide particles for
med at 1790 K contained trapped manganese at the internal pores.