E. Vanfaassen, EXACT TREATMENT OF INTERFACE FLUCTUATIONS IN A 2-DIMENSIONAL EMULSION, Nuovo cimento della Societa italiana di fisica. D, Condensed matter,atomic, molecular and chemical physics, biophysics, 16(9), 1994, pp. 1595-1599
We present a model for a polydisperse ensemble of two-dimensional drop
lets wich accounts for the effects of arbitrarily large distortions of
the droplet shape. Interactions within a droplet include bending rigi
dity and spontaneous curvature. Interactions between droplets are omit
ted. Even at high temperatures, the effects of the shape fluctuations
on the droplet size distribution remain small, as they are dominated b
y the contributions from the mixing entropy. In contrast, shape fluctu
ations lead to a pronounced peak in thermodynamic quantities like spec
ific heat. This peak occurs at temperatures where thermal excitations
become of the order of the bending energies of the droplet surface. Th
e fluctuation-dominate regime extends to temperatures far lower than e
xpected from a mean-field calculation.