NOVEL LIGANDS FOR ELECTRON-TRANSFER TRANSITION-METAL COMPLEXES

Citation
P. Piotrowiak et al., NOVEL LIGANDS FOR ELECTRON-TRANSFER TRANSITION-METAL COMPLEXES, Bulletin of the Polish Academy of Sciences. Chemistry, 42(4), 1994, pp. 445-453
Citations number
10
Categorie Soggetti
Chemistry
ISSN journal
02397285
Volume
42
Issue
4
Year of publication
1994
Pages
445 - 453
Database
ISI
SICI code
0239-7285(1994)42:4<445:NLFETC>2.0.ZU;2-E
Abstract
The synthesis of 4,5-diazospirobifluorene and 4,5-diazobifluorenyliden e, the first two members of a new family of transition metal ligands d esigned for the study of intramolecular electron and excitation transf er is reported. The description of the synthesis and the H-1-NMR assig nments are provided. The UV-VIS and fluorescence spectra of the new li gands, together with a brief discussion of their electronic properties are included.