REACTIONS BETWEEN PENTACYANONITROSYLFERRATE(2-) AND N-NUCLEOPHILES

Authors
STOCHEL G STOPA G STASICKA Z
Citation
G. Stochel et al., REACTIONS BETWEEN PENTACYANONITROSYLFERRATE(2-) AND N-NUCLEOPHILES, Bulletin of the Polish Academy of Sciences. Chemistry, 42(4), 1994, pp. 477-485
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Polish Academy of Sciences. Chemistry → ACNP
ISSN journal
02397285
Volume
42
Issue
4
Year of publication
1994
Pages
477 - 485
Database
ISI
SICI code
0239-7285(1994)42:4<477:RBPAN>2.0.ZU;2-O
Abstract
Reactions of pentacyanonitrosylferrate(2-) (nitroprusside, SNP) with v arious N-nucleophiles have been studied both spectroscopically and kin etically as a function of pH, concentration ratio, temperature and pre ssure. The final and intermediate products were characterized. Results of this work together with the literature data were used to propose t he overall mechanistic scheme for the reactions between nitroprusside and N-nucleophiles.