F. Langenhorst et al., THERMAL AND SHOCK METAMORPHISM OF THE TENHAM CHONDRITE - A TEM EXAMINATION, Geochimica et cosmochimica acta, 59(9), 1995, pp. 1835-1845
During the early episode of the solar system, the L6 chondrite Tenham
has been affected by intense thermal metamorphism. Microanalytical dat
a reveal homogeneous compositions of olivine (Fo(75)Fa(25)), enstatite
(En(79)Fs(19)Wo(2)), and diopside (En(47)Fs(8)Wo(45)). Using these da
ta, empirical pyroxene thermometers yield temperature estimates for th
is thermal metamorphism, ranging from 810 to 870 degrees C. Due to the
presence of thin shock veins, which contain the high-pressure phases
majorite and ringwoodite, the L6 chondrite Tenham is an instructive ex
ample for strong shock metamorphism. In contrast to previous transmiss
ion electron microscopy (TEM) studies, which concentrated on these sho
ck veins, we also systematically characterized the shock signature of
the silicates occulting in the bulk of Tenham. Plagioclase is either p
ervaded by thin (200 nm), amorphous lamellae, so-called planar deforma
tion features (''PDFs''), or it is transformed to maskelynite, a diapl
ectic glass of feldspar composition. In olivine, shock deformation has
caused the formation of irregular and planar fractures and the activa
tion of numerous (2 x 10(14) m(-2)) c dislocations in the glide planes
(100) and {110}; energetically favorable but less mobile a dislocatio
ns are totally absent. Fracturing in olivine is interpreted as the cau
se of dislocation formation. A low dislocation density (<10(12) m(-2))
and clinoenstatite lamellae have been detected in orthornstatite. Alt
hough other formation mechanisms are known for the ortho-/clino-enstat
ite inversion, a shock origin is most reasonable in this case because
of the presence of strong shock damage in the other silicates. Diopsid
e displays the greatest diversity of shock defects: mechanical twins p
arallel to (100) and (001), numerous dislocations, and PDFs. The predo
minant glide system of dislocations is (100)[001], but the {110}[001]
glide system is also present to a lesser extent. To our knowledge, we
report here on the first evidence of thin (less than or equal to 50 nm
), amorphous lamellae in naturally shocked diopside. These PDFs are or
iented parallel to {$$($) over bar 221} and {221}. Fine-grained (<2-3
mu m), polycrystalline aggregates of the high-pressure spinels, majori
te and ringwoodite, were observed in a thin shock vein. Majorite is de
fect-free, whereas ringwoodite contains several stacking faults parall
el to {110} planes. Microanalyses show that both phases are less homog
eneous than olivines and pyroxenes. This and the small grain sizes sug
gest a rapid crystallization of majorite and ringwoodite from a high-p
ressure melt, The stacking faults in ringwoodite are, hence, interpret
ed as growth defects. The results of this study substantiate that the
shock pressure in Tenham is heterogeneously distributed, ranging from
approximately 25 to 45 GPa. The formation of shock veins is not only a
scribed to pressure excursions, but mainly to the high shear stresses
resulting from the different shock impedances of Tenham's mineral cons
tituents.