The population and depopulation of the lowest electron-hole pair state
s have been investigated in CdSe and CdSSe quantum dots by time-resolv
ed luminescence experiments on a picosecond time scale, Auger-like sca
ttering processes within the two-pair system created under high excita
tion present an efficient relaxation mechanism. In nanosecond pump-and
-probe experiments the absorption bleaching has been investigated up t
o the evidence of gain. Gain has been observed both for quantum dots w
ith radii below and above the Bohr radius.