VOLCANIC clouds are an important natural hazard to aircraft(1), and ho
st chemical reactions that interest both volcanologists(2,3) and atmos
pheric scientists(4-6). Ice has been suggested as a possible component
of eruption clouds', but there has been no direct evidence for its pr
esence. Here we report the detection, using a satellite-borne infrared
sensor, of greater than or similar to 2 million tonnes of ice in the
cloud produced by the September 1994 eruption of Rabaul volcano, in Pa
pua New Guinea. The cloud also contained relatively low levels of sulp
hur dioxide (80+/-50 kilotonnes), compared with other stratospheric er
uption clouds. The unusual aspects of this cloud may be related to the
entry of sea water into the volcanic vent, and its participation in t
he eruption column. Past eruptions that occurred in similar (coastal)
settings, such as those of Krakatau and Santorini, might have had less
effect on the atmosphere than their volume alone would suggest, becau
se the presence of ice may decrease the residence time of ash and sulp
hur in the atmosphere. In addition, the ability of ice to mask the cha
racteristic spectral signature of volcanic ash will increase the diffi
culty of designing airborne ash detection systems for aviation safety.