J. Chrost et al., SURFACE DANGLING BOND STATE IN SI(111) AND EPITAXIAL BETA-FESI2 FILMS- A COMPARATIVE PHOTOELECTRON-SPECTROSCOPY STUDY, Surface science, 330(1), 1995, pp. 34-40
The surface of beta-FeSi2(101) grown on Si(111) contains surface state
s, located at about 0.3 eV below the Fermi level, which are related to
Si adatoms. These adatoms, which have been identified as atomic size
protrusions in STM images, are arranged in different surface reconstru
ctions. From hydrogenation experiments the average density of surface
states has been determined. It turns out to be comparable to the densi
ty of adatoms on Si(111)7 X 7. When the dangling bonds are saturated w
ith hydrogen, the beta-FeSi2 surface is efficiently passivated against
oxidation.