SMOKE SUPPRESSION FOR POLY(VINYL CHLORIDE) BY IRON-ORGANIC POLYMER SYSTEMS

Citation
K. Sekigawa et al., SMOKE SUPPRESSION FOR POLY(VINYL CHLORIDE) BY IRON-ORGANIC POLYMER SYSTEMS, Journal of organometallic chemistry, 494(1-2), 1995, pp. 1-4
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
494
Issue
1-2
Year of publication
1995
Pages
1 - 4
Database
ISI
SICI code
0022-328X(1995)494:1-2<1:SSFPCB>2.0.ZU;2-N
Abstract
Polyvinylferrocene mixed with poly(methyl methacrylate) or polystyrene (9:1 weight ratio) and 1,1'-dibenzylferrocene were found to exhibit e fficient smoke-suppressing properties for low filler plasticized poly( vinyl chloride) at the 0.3-3.0 wt.% loading level of Fe. On heat treat ment under argon, poly(vinyl chloride) homogenized with polyvinylferro cene produced predominantly alpha-Fe particles together with carboniza tion product, whereas in air alpha-Fe2O3 was formed preferentially wit hout the formation of carbonization product.