SYNTHESIS AND SOME REACTIONS OF MIXED (-)-MENTHYLTIN HYDRIDES

Authors
PODESTA JC CHOPA AB RADIVOY GE VITALE CA
Citation
Jc. Podesta et al., SYNTHESIS AND SOME REACTIONS OF MIXED (-)-MENTHYLTIN HYDRIDES, Journal of organometallic chemistry, 494(1-2), 1995, pp. 11-16
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
494
Issue
1-2
Year of publication
1995
Pages
11 - 16
Database
ISI
SICI code
0022-328X(1995)494:1-2<11:SASROM>2.0.ZU;2-1
Abstract
The synthesis and physical properties of dineophyl(-)menthyltin (4) an d methylneophyl (-)menthyltin (9) hydrides as well as that of their or ganotin precursors are described. Whereas the reduction of acetophenon e with 4 afforded (-)-(S)-1-phenylethanol in 40% ee, the reduction of the same ketone with dimethyl(-)menthyltin hydride yielded the alcohol with only a 7% ee. Full H-1,C-13, and Sn-119 NMR data are given.