MODES OF COMPLEXATION OF NON-SUBSTITUTED AND SUBSTITUTED TETRAAZAMACROCYCLES WITH GROUP-6 METAL-CARBONYLS - X-RAY STRUCTURE OF [(PERMETHYLCYCLAM)MO(CO)(4)]

Authors
PATINEC V YAOUANC JJ CLEMENT JC HANDEL H ABBAYES HD KUBICKI MK
Citation
V. Patinec et al., MODES OF COMPLEXATION OF NON-SUBSTITUTED AND SUBSTITUTED TETRAAZAMACROCYCLES WITH GROUP-6 METAL-CARBONYLS - X-RAY STRUCTURE OF [(PERMETHYLCYCLAM)MO(CO)(4)], Journal of organometallic chemistry, 494(1-2), 1995, pp. 215-222
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
494
Issue
1-2
Year of publication
1995
Pages
215 - 222
Database
ISI
SICI code
0022-328X(1995)494:1-2<215:MOCONA>2.0.ZU;2-U
Abstract
Reactions of complexation of tetraazamacrocycles L with Group 6 metal carbonyls [M(CO)(6)](M = Cr, Mo, or W) lead to [LM(CO)(4)], [LM(CO)(3) ] or [LM(CO)(2)] entities, depending bath on the size of the macrocycl e and on the metal M. The structure of one representative complex [(pe rmethylcyclam)Mo(CO)(4)] has been determined by X-ray diffraction (per methylcyclam: 11-tetramethyl-1,4,8,11-tetraazacyclotetradecane).