ITA
ENG

HYDROLYSIS OF (PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(IV) CARBAMATES - X-RAY STRUCTURE OF [(CP-ASTERISK-TI(ETA(2)-O(2)CNET(2)))(2)(MU-O)(2)]

Authors

GOMEZSAL P IRIGOYEN AM MARTIN A MENA M MONGE M YELAMOS C

Citation

P. Gomezsal et al., HYDROLYSIS OF (PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(IV) CARBAMATES - X-RAY STRUCTURE OF [(CP-ASTERISK-TI(ETA(2)-O(2)CNET(2)))(2)(MU-O)(2)], Journal of organometallic chemistry, 494(1-2), 1995, pp. 19-21

Citations number

Categorie Soggetti

Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear

Journal title

Journal of organometallic chemistry → ACNP

ISSN journal

0022328X

Volume

494

Issue

1-2

Year of publication

1995

Pages

19 - 21

Database

ISI

SICI code

0022-328X(1995)494:1-2<19:HO(C-X>2.0.ZU;2-S

Abstract

Complexes [CpTi(NR(2))(3)] (Cp* = eta(5)-C(5)Me(5); R = Me or Et) rea ct with CO2 to give the corresponding insertion products [CpTi(eta(2) -O(2)CNR(2))(3)] (R = Me (1), Et (2)). When solutions of 1-2 are expos ed to wet air a hydrolytic process takes place and leads to the format ion of the [{CpTi(eta(2)-O(2)CNR(2))}(2)(mu-O)(2)] (R = Me (3), Et (4 )). The molecular structure of 4 has been established by single crysta l X-ray analysis.