H. Fujikake et al., UNIFORM MICRODROPLET FORMATION OF POLYMER-DISPERSED LIQUID-CRYSTAL USING UNDERCOATING FILMS, Electronics & communications in Japan. Part 2, Electronics, 77(12), 1994, pp. 48-58
It is found that liquid crystal microdroplets become uniform and their
sizes are reduced if the substrates are coated with some undercoating
film before forming polymer-dispersed liquid crystal using the photop
olymerization-induced phase separation method. In this study, polyviny
lalcohol was used for the undercoating film because it has good wettin
g property to the liquid-crystal material, resulting in suppression of
nonuniform nucleation and growth of the microdroplets. In the polymer
-dispersed liquid crystal formed under ultraviolet (UV) irradiation wi
th 10 mW/cm(2), the diameter of the liquid-crystal droplets varied in
a range up to approximately 6 mu m without using an undercoating film
while the variation of the droplet diameters became less than 2 mu m w
hen the undercoating film was used. As a result, the threshold charact
eristic in the electrooptic property, response time, spatial resolutio
n, and film uniformity were improved drastically by using the undercoa
ting film. By using the polymer-dispersed liquid crystal formed in thi
s new method, a high limiting resolution (as high as 128 1p/mm) was ac
hieved. The polymer-dispersed liquid crystal formed in this way is exp
ected to be used for projection displays with high resolution and high
brightness.