Jm. Smith et al., TRACE DETECTION OF NO2 BY FREQUENCY-MODULATION-ENHANCED MAGNETIC ROTATION SPECTROSCOPY, Journal of the Optical Society of America. B, Optical physics, 12(6), 1995, pp. 964-969
Frequency-modulation-enhanced magnetic rotation spectroscopy has been
shown to be a sensitive and selective technique for detecting local co
ncentrations of gaseous NO2. Detection levels of 20 parts in 10(9) hav
e been achieved in the laboratory (in the presence of larger ambient a
tmospheric levels). Simple signal-processing algorithms, demonstrated
here, promise detection levels at the parts-in-10(12) level. Improveme
nts are suggested for further optimization of the technique, and the e
ffects of background atmospheric NO2 levels are discussed.