5,10-DIHYDRO-SILANTHRENE AS A REAGENT FOR THE BARTON-MCCOMBIE REACTION

Authors
GIMISIS T BALLESTRI M FERRERI C CHATGILIALOGLU C BOUKHERROUB R MANUEL G
Citation
T. Gimisis et al., 5,10-DIHYDRO-SILANTHRENE AS A REAGENT FOR THE BARTON-MCCOMBIE REACTION, Tetrahedron letters, 36(22), 1995, pp. 3897-3900
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
22
Year of publication
1995
Pages
3897 - 3900
Database
ISI
SICI code
0040-4039(1995)36:22<3897:5AARFT>2.0.ZU;2-8
Abstract
The deoxygenation of secondary alcohols via thionoesters with the use of 5,10-dihydrosilanthrene as the radical reducing agent has been stud ied in detail. The ability of hydrogen donation of this silane has bee n measured using the one-carbon ring expansion of 1-(2-oxocyclopentyl) ethyl radical as a timing device.