Sv. Maklakov et al., THE CRITICAL TRANSITION BETWEEN PHASE-FORMATION MODES IN THE PYROLYSIS OF SILANE, Mendeleev communications, (3), 1995, pp. 120-123
A jump-wise transition between two different kinetic modes of phase fo
rmation in the course of silane pyrolysis has been found experimentall
y. In one mode the solid phase is formed as an aerosol, in the other a
s a film; the phenomenon can be reproduced by mathematical analysis of
a model mechanism.