We demonstrate that the synthesis of polymer complexes (PHAE-Al) occur
s between poly(hydroxyamino esters) (PHAEs) and aluminum by using the
conventional vacuum deposition method in the process of thin metal lay
er formation on the surface of the polymer. These complexes exhibit el
ectroluminescence similar in spectral characteristics to the well-know
n low-molecular tris(8-quinolinolato) aluminum complex (Alq(3)). Spect
ral and electrical data for the polymer light-emitting diodes Al/PHAE-
Al/PHAE/PANI with PHAEs of various chemical structure are reported.