NEW APPROACH TO QUANTUM DYNAMICS - RECURSIVE, AVERAGE-CASE COMPLEXITY, DISTRIBUTED APPROXIMATING FUNCTIONAL METHOD FOR TIME-INDEPENDENT WAVEPACKET FORMS OF SCHRODINGER AND LIPPMANN-SCHWINGER EQUATIONS
Yh. Huang et al., NEW APPROACH TO QUANTUM DYNAMICS - RECURSIVE, AVERAGE-CASE COMPLEXITY, DISTRIBUTED APPROXIMATING FUNCTIONAL METHOD FOR TIME-INDEPENDENT WAVEPACKET FORMS OF SCHRODINGER AND LIPPMANN-SCHWINGER EQUATIONS, Chemical physics letters, 238(4-6), 1995, pp. 387-394
A new approach to quantum dynamics is presented which addresses the fu
ndamental difficulty of exponential growth of computational complexity
with the dimensionality of the system. A general recursive polynomial
treatment of the time-independent full Green operator, the average-ca
se complexity approach to multi-dimensional integration, and the conti
nuous distributed approximating functional representation of the Hamil
tonian are the three ingredients of the approach. Calculations for col
linear H + H-2 reactive scattering are presented to illustrate the met
hod.