In order to investigate the nucleation phenomena on the surface of mol
d wall, two types of surface condition of chill blocks have been immer
sed in the molten steel. When the mold A, of which surface is flat, wa
s immersed, irregular shell was obtained and very-fine-solidified stru
cture which locates in the thicker region was observed on the chill bl
ock side of the shell. On the other hand, when the mold B, of which su
rface is rough, was immersed, uniform shell was obtained and regular c
olumnar dendritic structure was observed. The shape of very-fine-solid
ified structure (mold A) is hemisphere. The degree of recalescense for
nucleation dose to the flat chill block measured by fine thermocouple
was 20K, which is larger than that close to the rough chill block. Th
ese results may come from the difference oi nucleation phenomena on th
e mold surface. The details are followings. : When the flat chill bloc
k is immersed, nucleation on the surface is difficult to occur, theref
ore undercooling becomes large, In the same time the undercooled regio
n becomes large. The dendrites, growing rapidly in the largely underco
oled, are very fine and they correspond to the thicker part of shell.
Finally shell with irregular thickness is obtained. When the rough chi
ll block is immersed, nucleation is easy to perform, therefore underco
oling for nucleation is small and uniform columnar dendritic structure
is observed.