SYNTHESIS AND SPECTRAL INVESTIGATION OF RARE EARTH(III) COMPLEXES OF AMIDO ACID LIGAND DERIVED FROM 2,4-DINITROPHENYLHYDRAZINE

Authors
SHEN X XIE YY WANG LP CHEN GZ ZHU CZ
Citation
X. Shen et al., SYNTHESIS AND SPECTRAL INVESTIGATION OF RARE EARTH(III) COMPLEXES OF AMIDO ACID LIGAND DERIVED FROM 2,4-DINITROPHENYLHYDRAZINE, Synthesis and reactivity in inorganic and metal-organic chemistry, 25(4), 1995, pp. 499-509
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
25
Issue
4
Year of publication
1995
Pages
499 - 509
Database
ISI
SICI code
0094-5714(1995)25:4<499:SASIOR>2.0.ZU;2-X
Abstract
Fourteen rare earth (III) complexes REL(3) . nH(2)O (where RE = Sc, n = 5; RE = Y, La, Ce, Sm; Eu, Gd, Tb, Dy, Ho, Er, Yb, n = 6; RE = Pr, N d, n = 4; HL = phenyl)amino-acetyl-2',4'-dinitrophenylhydrazine), have been synthesized and characterized by elemental analyses, conductance measurements, magnetic moments, IR,H-1 NMR, electronic spectra, TG an d DTA. Their nephelauxetic ratio (beta), bonding parameter (b(1/2), Si nha's parameter (delta%) and covalency angular overlap parameter (eta) have been determined for the Pr3+, Nd3+ and Er3+ complexes.