S. Iso et al., EXTRACTION OF URANIUM(VI) FROM NITRIC-ACID SOLUTION INTO SUPERCRITICAL CARBON-DIOXIDE CONTAINING TRI-N-BUTYLPHOSPBATE, Chemistry Letters, (5), 1995, pp. 365-366
Uranium(VI) in the aqueous solution of (3 - 6) M (1 M = 1 mol dm(-3))
HNO3 + 3 M LiNO3 was extracted into supercritical CO2 fluid containing
3 vol% of tri-n-butylphosphate (TBP) at 60 degrees C and (1.5 - 3.5)
x 10(7) Pa. Rapid and complete removal of CO2 medium from the extract
was attained by gasification of CO2 at atmospheric temperature and pre
ssure.