Jm. Lee et al., OBSERVED STRATOSPHERIC PROFILES AND STRATOSPHERIC LIFETIMES OF HCFC-141B AND HCFC-142B, Geophysical research letters, 22(11), 1995, pp. 1369-1372
We present here the first stratospheric profile measurements of HCFC-1
41b (CH3-CFCl2) and HCFC-142b (CH3-CF2Cl). From the measurements we de
rive a stratospheric lifetime of 68 +/- 11 years for HCFC-14lb acid an
estimated minimum stratospheric lifetime for HCFC-142b of 138 years r
elative to an N2O lifetime of 110 y. (These results increase to 104 +/
- 17 y and >211 y respectively for an N2O lifetime of 168 y). Neither
HCFC-141b nor HCFC-142b is now in equilibrium in the stratosphere, due
to rapidly increasing emissions in recent years.