STEREOCONTROLLED SYNTHESIS OF ENANTIOMERICALLY PURE 2-DIENYL SULFOXIDES VIA PALLADIUM-CATALYZED COUPLING REACTIONS

Authors
PALEY RS WEERS HL FERNANDEZ P DELAPRADILLA RF CASTRO S
Citation
Rs. Paley et al., STEREOCONTROLLED SYNTHESIS OF ENANTIOMERICALLY PURE 2-DIENYL SULFOXIDES VIA PALLADIUM-CATALYZED COUPLING REACTIONS, Tetrahedron letters, 36(21), 1995, pp. 3605-3608
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
21
Year of publication
1995
Pages
3605 - 3608
Database
ISI
SICI code
0040-4039(1995)36:21<3605:SSOEP2>2.0.ZU;2-O
Abstract
Enantiopure 2-sulfinyl dienes can be prepared via regio- and stereosel ective hydrostannylation of alkynylsulfoxides; after conversion to the corresponding vinyliodides these substrates may be coupled with vinyl stannanes via Stille methodology in the presence of BHT.