COPPER CYANIDE CATALYZED PALLADIUM COUPLING OF ALPHA-LITHIO AMINES AND ARYL IODIDES

Authors
DIETER RK LI SJ
Citation
Rk. Dieter et Sj. Li, COPPER CYANIDE CATALYZED PALLADIUM COUPLING OF ALPHA-LITHIO AMINES AND ARYL IODIDES, Tetrahedron letters, 36(21), 1995, pp. 3613-3616
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
21
Year of publication
1995
Pages
3613 - 3616
Database
ISI
SICI code
0040-4039(1995)36:21<3613:CCCPCO>2.0.ZU;2-D
Abstract
Treatment of alpha-aminoalkyllithium reagents with aryl iodides in the presence of catalytic amounts of CuCN and PdCl2(PPh(3))(2) or [(p-MeO C(6)H(4))(3)P]Pd-4 affords 2-aryl substituted amines in modest to good yields. Coupled products are obtained with electron rich aryl iodides and the reaction fails with electron poor aryl halides.