HYDROPEROXIDE-MEDIATED C-C BOND FORMATION - SYNTHESIS OF 1,2-DIOXOLANES FROM ALKOXYHYDROPEROXIDES IN THE PRESENCE OF LEWIS-ACIDS

Authors
DUSSAULT PH ZOPE U
Citation
Ph. Dussault et U. Zope, HYDROPEROXIDE-MEDIATED C-C BOND FORMATION - SYNTHESIS OF 1,2-DIOXOLANES FROM ALKOXYHYDROPEROXIDES IN THE PRESENCE OF LEWIS-ACIDS, Tetrahedron letters, 36(21), 1995, pp. 3655-3658
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
21
Year of publication
1995
Pages
3655 - 3658
Database
ISI
SICI code
0040-4039(1995)36:21<3655:HCBF-S>2.0.ZU;2-Q
Abstract
Lewis-acid activation of ozonolysis-derived hydroperoxyketals affords intermediate hydroperoxycarbenium ions (protonated carbonyl oxides) wh ich undergo addition of allyltrimethylsilane to directly afford 1,2-di oxolanes.