A STEREOSELECTIVE ROUTE TO 1-CHLORO-1-HALO-ENYNES, VERSATILE PRECURSORS FOR THE SYNTHESIS OF CHLOROENEDIYNES AND ENETRIYNES

Authors
ALAMI M CROUSSE B LINSTRUMELLE G
Citation
M. Alami et al., A STEREOSELECTIVE ROUTE TO 1-CHLORO-1-HALO-ENYNES, VERSATILE PRECURSORS FOR THE SYNTHESIS OF CHLOROENEDIYNES AND ENETRIYNES, Tetrahedron letters, 36(21), 1995, pp. 3687-3690
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
21
Year of publication
1995
Pages
3687 - 3690
Database
ISI
SICI code
0040-4039(1995)36:21<3687:ASRT1V>2.0.ZU;2-G
Abstract
1-Chloro-1-halo-enynes, readily available by metallation of (E)-chloro enynes, undergo sequential coupling with terminal alkynes under Pd-cat alysis to produce stereoselectively chloroenediynes and enetriynes in good yields.