DIASTEREOSELECTIVE BROMODIFLUOROMETHYLATION OF CHIRAL IMIDE ENOLATES VIA INSERTION OF DIFLUOROCARBENE

Authors
ISEKI K ASADA D TAKAHASHI M NAGAI T KOBAYASHI Y
Citation
K. Iseki et al., DIASTEREOSELECTIVE BROMODIFLUOROMETHYLATION OF CHIRAL IMIDE ENOLATES VIA INSERTION OF DIFLUOROCARBENE, Tetrahedron letters, 36(21), 1995, pp. 3711-3714
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
21
Year of publication
1995
Pages
3711 - 3714
Database
ISI
SICI code
0040-4039(1995)36:21<3711:DBOCIE>2.0.ZU;2-U
Abstract
The bromodifluoromethylation of lithium enolates of chiral N-acyloxazo lidinones via the insertion of difluorocarbene proceeds with good dias tereomeric Excess (68-92% de).