It is established that in natural and technogenic environment a new ge
ochemical groundwater type appears presented by the ammonia bearing wa
ters with the predominant ammonia content in respect of other cations.
The increase of ammonia content is governed by the following geochemi
cal factors: decrease of groundwater redox potential; pH decrease; amm
onification of organic matter; increase of water mineralisation. Main
geochemical types of the natural ammonia bearing ground waters are rec
ognised: acidic waters of different origin; highly mineralised brines
of salt-rock bearing structures; brines of oil-gas bearing regions; an
oxygen waters of upper water bearing strata in artesian basins. The fo
rmation of polluted groundwaters is governed by the existence of inten
sive ammonia source in the industrial and agriculture wastes. Three ma
in types of such waters are distinguished: acidic waters with high red
ox potential; near neutral waters with high organic matter content and
low positive values of redox potential; alkaline waters with low posi
tive and negative values of redox potential. It is concluded that in r
ecent time the ground waters are subjected to ammonia content increase
resulted in the deterioration of its environmental conditions. It is
governed by the pollution of upper water bearing strata and successive
decrease of its redox potential.