THE INFRARED-SPECTRUM AND CONFORMATION OF ACETONE OXIME VINYL ETHER

Authors
SOHLBERG K LEARY SP OWEN NL TROFIMOV BA
Citation
K. Sohlberg et al., THE INFRARED-SPECTRUM AND CONFORMATION OF ACETONE OXIME VINYL ETHER, Vibrational spectroscopy, 13(2), 1997, pp. 227-234
Citations number
13
Categorie Soggetti
Spectroscopy,"Chemistry Analytical","Chemistry Physical
Journal title
Vibrational spectroscopy → ACNP
ISSN journal
09242031
Volume
13
Issue
2
Year of publication
1997
Pages
227 - 234
Database
ISI
SICI code
0924-2031(1997)13:2<227:TIACOA>2.0.ZU;2-3
Abstract
The infrared spectrum of acetone oxime vinyl ether (AOVE) has been stu died for the gaseous, Liquid and solid phases as well as in an inert m atrix at low temperatures. HF-SCF calculations have been carried out o n AOVE and they predict the presence of one dominant rotamer with a he avy atom planar (trans) structure. The infrared spectrum is consistent with this conclusion, and assignments are made to many of the normal modes. Specific assignments have also been made for all the observed H -1 and C-13 NMR spectral lines.