ESR STUDY OF RADIATION-INDUCED ORGANIC RADICALS IN CACO3

Authors
Citation
A. Kai, ESR STUDY OF RADIATION-INDUCED ORGANIC RADICALS IN CACO3, Applied radiation and isotopes, 47(11-12), 1996, pp. 1483-1487
Citations number
14
Categorie Soggetti
Nuclear Sciences & Tecnology","Radiology,Nuclear Medicine & Medical Imaging","Chemistry Inorganic & Nuclear
Journal title
Applied radiation and isotopes
ISSN journal
09698043 → ACNP
Volume
47
Issue
11-12
Year of publication
1996
Pages
1483 - 1487
Database
ISI
SICI code
0969-8043(1996)47:11-12<1483:ESOROR>2.0.ZU;2-U
Abstract
Radiation-induced organic radicals in CaCO3 doped with gamma-aminobuty ric acid and glycine, and Li2CO3 with adsorbed glycine were investigat ed by electron spin resonance. Isopropyl radicals occurred in CaCO3 do ped with gamma-aminobutyric acid. A signal at g = 2.0046 exhibiting in teraction with a proton, a nitrogen and another proton was detected in glycine-doped CaCO3. The signal shows strong anisotropy of interactio n with the first proton. The signal was also found in Li2CO3 with adso rbed glycine. The result revealed that amino acid molecules are on the surface of CaCO3. Copyright (C) 1996 Elsevier Science Ltd