EMPIRICAL CORRELATION OF C-13 NMR CHEMICAL-SHIFT WITH ORIENTATIONAL ORDERING IN SOLID KNC60(THF)(M)(N=1-3)

Authors
CHEN J HUANG ZE CAI RF SHAO QF YE HJ
Citation
J. Chen et al., EMPIRICAL CORRELATION OF C-13 NMR CHEMICAL-SHIFT WITH ORIENTATIONAL ORDERING IN SOLID KNC60(THF)(M)(N=1-3), Solid state communications, 95(4), 1995, pp. 233-237
Citations number
12
Categorie Soggetti
Physics, Condensed Matter
Journal title
Solid state communications → ACNP
ISSN journal
00381098
Volume
95
Issue
4
Year of publication
1995
Pages
233 - 237
Database
ISI
SICI code
0038-1098(1995)95:4<233:ECOCNC>2.0.ZU;2-P
Abstract
KnC60(THF)(m) (n=1-3, m=n) have been prepared via solution-phase route . Variable temperature C-13 NMR data reveal that there exists a strong correlation of C-13 NMR chemical shift with the degree of orientation al order of C-60(n-) in these materials. The implications of this obse rvation to the origin of down-field chemical shifts (relative to neutr al C-60) in fullerene anions are discussed briefly.