PREPARATION AND PROPERTIES OF INCLUSION-COMPOUNDS OF BETA-CYCLODEXTRIN WITH (ETA(5)-PYRROLYL)TRICARBONYLMANGANESE(I) AND ITS ANALOGS

Authors
SONG LX MENG QJ YOU XZ
Citation
Lx. Song et al., PREPARATION AND PROPERTIES OF INCLUSION-COMPOUNDS OF BETA-CYCLODEXTRIN WITH (ETA(5)-PYRROLYL)TRICARBONYLMANGANESE(I) AND ITS ANALOGS, Synthesis and reactivity in inorganic and metal-organic chemistry, 25(5), 1995, pp. 671-677
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
25
Issue
5
Year of publication
1995
Pages
671 - 677
Database
ISI
SICI code
0094-5714(1995)25:5<671:PAPOIO>2.0.ZU;2-A
Abstract
One-to-one inclusion compounds of beta-cyclodextrin(beta-CD, host) wit h (eta(5)-pyrrolyl)tricarbonylmanganese(I) and its analogues(guests) w ere obtained in a crystalline state and characterized by elemental ana lysis, H-1 NMR and IR spectra, and DSC measurements. The host-guest in clusion compounds are thermally stable and do not liberate the guest o n heating at 110 degrees C in vacuo. These represent the first example s of cyclodextrin inclusion compounds with transition metal heterocycl ic complexes.