Dl. Mao et al., ON THE SIGMOIDAL SHAPE OF CURRENT-VOLTAGE CURVES OF PHOTOELECTROCHEMICAL SOLAR-CELLS, Journal of the Electrochemical Society, 142(6), 1995, pp. 1869-1873
Current-voltage (J-V) curves of n-GaAs/KOH(aq)-Se-2(2-)/Se2- and n-Si/
acetone-LiClO4-Fc(+/0) (ferrocenium ion/ferrocene) solar cells exhibit
sigmoidal shapes near the open-circuit potential. J-V and flatband po
tential measurements indicate that the deviation of the J-V curves fro
m the ideal square-like shape to S shape is due to the light-induced d
isplacement of the bandedges. Analytical expressions describing the de
pendence of light-induced bandedge shifts on the anodic photocurrent,
the density of surface states, and the interfacial charge-transfer vel
ocity are derived and verified experimentally Application of the expre
ssions to J-V data yields quantitative information on the kinetics of
interfacial charge transfer.