V. Mastelaro et al., COMPARATIVE EXAFS STUDY OF (AG(2)X)(Y)(AS(2)X(3))(1-Y) GLASSES (X=SE OR S), Journal of non-crystalline solids, 185(3), 1995, pp. 274-282
The local order of ionic (Ag(2)X)(y)(As(2)X(3))(1-y) glasses (X = Se o
r S) has been studied in a wide composition range using X-ray absorpti
on fine structure spectroscopy. The silver atoms remain in a well defi
ned chalcogenide atom surroundings made of two bonded atoms (R(Ag-Se)
approximate to 2.58 Angstrom, R(Ag-S) approximate to 2.46 Angstrom). N
o significant differences between sulphide and selenide glasses were o
bserved.