OXIDATIVE CLEAVAGE OF THE TE-TE BOND IN ETA(2)-DITELLURIDO COMPLEXES - SYNTHESES AND STRUCTURES OF M(PME(3))(4)(ETA(2)-TE-2)H-2 (M=MO, W)

Authors
MURPHY VJ RABINOVICH D HALKYARD S PARKIN G
Citation
Vj. Murphy et al., OXIDATIVE CLEAVAGE OF THE TE-TE BOND IN ETA(2)-DITELLURIDO COMPLEXES - SYNTHESES AND STRUCTURES OF M(PME(3))(4)(ETA(2)-TE-2)H-2 (M=MO, W), Journal of the Chemical Society, Chemical Communications, (11), 1995, pp. 1099-1100
Citations number
39
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
11
Year of publication
1995
Pages
1099 - 1100
Database
ISI
SICI code
0022-4936(1995):11<1099:OCOTTB>2.0.ZU;2-O
Abstract
The eta(2)-ditellurido derivatives, M(PMe(3))(4)(eta(2)-Te-2)H-2 (M = MO, W) are synthesized by the reactions of M(PMe(3))(5)H-2 With elemen tal tellurium; the conversion of M(PMe(3))(4)(eta(2)-Te-2)H-2 to the t erminal tellurido complexes M(PMe(3))(4)(Te)(2) provides an unpreceden ted example of a transformation that involves oxidative cleavage of a ditellurido ligand at a single metal centre.