CATALYTIC CONVERSIONS IN WATER - O-17, (H-1)P-31 AND CL-35 NMR-STUDY OF A NOVEL STOICHIOMETRIC REDOX REACTION BETWEEN PDCL2, TPPTS AND H2O [TPPTS=P(C6H4-M-SO3NA)(3)]

Authors
PAPADOGIANAKIS G PETERS JA MAAT L SHELDON RA
Citation
G. Papadogianakis et al., CATALYTIC CONVERSIONS IN WATER - O-17, (H-1)P-31 AND CL-35 NMR-STUDY OF A NOVEL STOICHIOMETRIC REDOX REACTION BETWEEN PDCL2, TPPTS AND H2O [TPPTS=P(C6H4-M-SO3NA)(3)], Journal of the Chemical Society, Chemical Communications, (11), 1995, pp. 1105-1106
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
11
Year of publication
1995
Pages
1105 - 1106
Database
ISI
SICI code
0022-4936(1995):11<1105:CCIW-O>2.0.ZU;2-H
Abstract
O-17, {H-1}P-31 and Cl-35 NMR are used to investigate the mechanism of the reaction of PdCl2 with tppts [tppts = P(C6H4-m-SO3Na)(3)] in O-17 enriched water to give the novel complex [PdCl(tppts)3](+) 1, which i s reduced quantitatively to Pd(tppts)(3) 2 with tppts (8 d, 25 degrees C); with CO (2 bar) reduction to 2 is quantitative in 5 min at 25 deg rees C.