COMPETING PATHWAYS IN THE PHOTOLYTIC CYCLOADDITION REACTIONS OF N-ETHOXYCARBONYLAZEPINE TO [60]FULLERENE - FORMATION OF [2+4] AND [2+6] PHOTOADDUCTS

Authors
BANKS MR CADOGAN JIG GOSNEY I HODGSON PKG LANGRIDGESMITH PRR MILLAR JRA PARKINSON JA SADLER IH TAYLOR AT
Citation
Mr. Banks et al., COMPETING PATHWAYS IN THE PHOTOLYTIC CYCLOADDITION REACTIONS OF N-ETHOXYCARBONYLAZEPINE TO [60]FULLERENE - FORMATION OF [2+4] AND [2+6] PHOTOADDUCTS, Journal of the Chemical Society, Chemical Communications, (11), 1995, pp. 1171-1172
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
11
Year of publication
1995
Pages
1171 - 1172
Database
ISI
SICI code
0022-4936(1995):11<1171:CPITPC>2.0.ZU;2-H
Abstract
The photochemical reaction between [60]fullerene and N-ethoxycarbonyla zepine, formed in situ by light-induced decomposition of ethyl azidofo rmate in benzene, produces two photoadducts in the ratio of 4:1 by for mal [2 + 4] and [2 + 6] cycloaddition reactions as established by a se ries of high-field (600 MHz) NMR experiments.