IN(II)-(MESO-TETRAPHENYLPORPHYRINATO)RHODIUM(III), A PORPHYRIN DERIVATIVE WITH AN RH-SN BOND

Authors
LICOCCIA S PAOLESSE R BOSCHI T
Citation
S. Licoccia et al., IN(II)-(MESO-TETRAPHENYLPORPHYRINATO)RHODIUM(III), A PORPHYRIN DERIVATIVE WITH AN RH-SN BOND, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 833-835
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
5
Pages
833 - 835
Database
ISI
SICI code
0108-2701(1995)51:<833:IAPD>2.0.ZU;2-V
Abstract
The structure of the title compound, trichloro-2 kappa(3)Cl-(5,10,15,2 0-tetraphenylporphyrinato- 1 ppa(4)N(21,22,)(23,24))rhodium(III)tin(II )(Rh-Sn), [RhSnCl3(C44H28N4)], consists of well separated units in whi ch the Rh atom is five-coordinate at the center of a square-pyramidal polyhedron with the Sn atom at the top. The macrocylic unit is planar with the Rh atom displaced by only 0.02 Angstrom from the ring plane. The Rh-Sn bond length is 2.450 (1) Angstrom.