MOLECULAR-STRUCTURE AND ABSOLUTE-CONFIGURATION OF 2,3-DIDEHYDRO-1-BETA,10-BETA-EPOXYPSILOSTACHYIN-B (ISOPAULITIN)

Authors
RODRIGUEZ JG PERALES A
Citation
Jg. Rodriguez et A. Perales, MOLECULAR-STRUCTURE AND ABSOLUTE-CONFIGURATION OF 2,3-DIDEHYDRO-1-BETA,10-BETA-EPOXYPSILOSTACHYIN-B (ISOPAULITIN), Journal of natural products, 58(4), 1995, pp. 564-569
Citations number
18
Categorie Soggetti
Chemistry,"Plant Sciences","Pharmacology & Pharmacy
Journal title
Journal of natural products → ACNP
ISSN journal
01633864
Volume
58
Issue
4
Year of publication
1995
Pages
564 - 569
Database
ISI
SICI code
0163-3864(1995)58:4<564:MAAO2>2.0.ZU;2-#
Abstract
The molecular structure, conformational analysis, and absolute configu ration of isopaulitin [1], a sesquiterpene lactone, have been determin ed by single-crystal X-ray diffraction analysis. The correlation betwe en the position and stereochemistry of the gamma-lactone fusion to the cycloheptane ring and the sign of the Cotton effect of the n-pi tran sition of the C=C-C=O chromophore in 1 has been analyzed.