Both as-implanted and annealed semiconducting FeSi2 samples fabricated
using ion beam synthesis technique were studied by transmission elect
ron microscopy. A continuous buried silicide layer with larger precipi
tates and sharper interfaces formed during annealing at 900 degrees C
for 18 h. Different orientation relationships between the silicide gra
ins and the silicon substrate were found. The existence of a large var
iety of parallel lattice plane pairs with the available small mismatch
es between the two phases results in these preferred orientation relat
ionships.