ON THE STABILITY OF THE ALEXANDER POLYMER BRUSH

Citation
Fj. Solis et Gt. Pickett, ON THE STABILITY OF THE ALEXANDER POLYMER BRUSH, Macromolecules, 28(12), 1995, pp. 4307-4312
Citations number
12
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
00249297
Volume
28
Issue
12
Year of publication
1995
Pages
4307 - 4312
Database
ISI
SICI code
0024-9297(1995)28:12<4307:OTSOTA>2.0.ZU;2-S
Abstract
We present a Lagrangian description of the deformations. of flat Alexa nder polymer brushes. An Alexander brush is one in which all polymer c hains are stretched from the base to the free surface of the brush. We analyze the linear stability of a grafted brush and a symmetric diblo ck lamella in a melt state. Both systems are unstable against plane-wa ve surface deformations of short wavelengths. Stability can be recover ed with the introduction of a small but finite surface tension.