A characteristic feature of the Si(111) (square-root3 x square-root3)R
30-degrees-Au surface is an intrinsically high density of domain walls
. Combining the complementary strengths of scanning tunneling microsco
py and X-ray standing waves it was possible to resolve the atomic stru
cture of the domain walls and the Si(111) (square-root3 x square-root3
)R30-degree-Au domains. A detailed structural model for the domain wal
ls is presented and compared to the experimental results. The model in
volves the coexistence of two kinds of Au trimers with different regis
tries and a separation of 0.5 angstrom normal to the (111) planes.