Electrons occupying surface states on the close-packed faces of noble
metals form a two-dimensional (2-d) nearly free electron gas. Because
this system is accessible to the scanning tunneling microscope (STM),
it provides a unique opportunity to study the local properties of low-
dimensional electrons. On Cu(111) we have observed standing wave patte
rns in the surface local density of states due to the quantum mechanic
al interference of surface state electrons scattering off of step edge
s and adsorbates. We find that Fe adatoms strongly scatter the surface
state and, as a result, are good building blocks for constructing ato
mic-scale barriers (''quantum corrals'') to confine the surface state
electrons. The barriers are constructed by individually positioning Fe
adatoms using the tip of a cold (4 K) STM. Tunneling spectroscopy per
formed inside of the corrals reveals discrete resonances, consistent w
ith sire quantization. A more quantitative understanding is obtained b
y accounting for the multiple scattering of surface state electrons wi
th the corrals' constituent adatoms. This scattering is characterized
by a complex phase shift which can be extracted from the electronic de
nsity pattern inside a quantum corral.