STEREOSPECIFIC CONVERSION OF H-PHOSPHONATES INTO PHOSPHORAMIDATES - THE USE OF VICINAL CARBON-PHOSPHORUS COUPLINGS FOR CONFIGURATIONAL DETERMINATION OF PHOSPHORUS

Authors
TOMOSKOZI I GACSBAITZ E OTVOS L
Citation
I. Tomoskozi et al., STEREOSPECIFIC CONVERSION OF H-PHOSPHONATES INTO PHOSPHORAMIDATES - THE USE OF VICINAL CARBON-PHOSPHORUS COUPLINGS FOR CONFIGURATIONAL DETERMINATION OF PHOSPHORUS, Tetrahedron, 51(24), 1995, pp. 6797-6804
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
24
Year of publication
1995
Pages
6797 - 6804
Database
ISI
SICI code
0040-4020(1995)51:24<6797:SCOHIP>2.0.ZU;2-1
Abstract
Separated P-diastereomers of H-phosphonate diesters gave exclusively o ne isomer of amidates on treatment with CCl4 + butylamine with inversi on of configuration. NOE experiments and the trend observed in (3)J(C2 -P) and (3)J(C4-P) couplings were applied for stereochemical assignmen t.